HI Xavier,
You are just rotating the Shin, but don’t forget that the children also move.
The rogue weights are likely lower in the hierarchy (ie – the DEF-Foot or the DEF-Toe)
Try rotating the Shin but then select the Foot and subtract from the other leg
Then do the same for the Toe.
The reason you can’t subtract those weights is that they aren’t a part of the group you are trying to subtract them from.
(Hope that makes sense)
Let us know if you’re still stuck – and post your file. I will show you.