@procyonlotor Thank you for taking the time to consider my request!
The upper arm bones are indeed parented to the clavicle, which is in following with a couple different tutorials. I will try clearing the parent to see how it goes, because I can see how it might be beneficial.
I have learned that the main rotation of a bone is around the x-axis. Of course, the shoulder is a rather complex joint, but I interpret this to mean that the up/down action of the arm should be around the x, making the forward to back action around the z. That said, given that this guy is a knuckle walker, it might make sense to adapt the roll to better suit the action. Also, the clavicles might want for better orientation,
I do have “Preserve volume” checked. 🙂